The very first Emperor Palpatine action figure was released by Kenner in 1983 as part of the vintage line-up for Return Of The Jedi. Two of the nicest representations of Darth Sidious/Palpatine were released during the Episode 1 toy line in 1999 as a holographic and a regular version. Below is a list of Senator Palpatine / Darth Sidous / Emperor Palpatine action figures.
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We recommend getting your figures from Entertainment Earth. They have been in business for over 20 years, they have a mint guarantee and understand collector's needs. Many of the figures on J.B. came from EE (yes, we pay for figures just like you) and always had a great experience. It's definitely worth to look at Entertainment Earth's Star Wars section!.